Table 4. Linearity, LOD, LOQ, and recovery of detected pesticides in grape matrix

Instrument	Pesticides	Linearity (R2)	LOD1) (mg/kg)	LOQ2) (mg/kg)	Recovery3) (%) (mean±RSD)
GC-MS/MS	Boscalid	1.0000	0.00062	0.00188	90.2±1.2
	Cyprodinil	0.9995	0.00133	0.00403	88.1±1.4
	Pyrimethanil	0.9998	0.00190	0.00577	80.5±2.7
	Tebuconazol	0.9998	0.00163	0.00493	90.1±1.4
LC-MS/MS	Acetamiprid	0.9968	0.00121	0.00367	90.2±1.8
	Azoxystrobin	0.9946	0.00092	0.00279	104.6±1.6
	Carbendazim	0.9938	0.00124	0.00377	76.3±2.0
	Dinotefuran	0.9937	0.00084	0.00254	91.4±4.4
	Etofenprox	0.9939	0.00159	0.00483	109.8±4.6
	Fenhexamid	0.9932	0.00216	0.00655	109.8±5.5
	Flubendiamide	0.9964	0.00227	0.00689	92.7±6.3
	Fludioxonil	0.9908	0.00264	0.00801	100.6±3.1
	Flufenoxuron	0.9941	0.00198	0.00601	82.6±5.0
	Flupyradifurone	0.9916	0.00244	0.00741	102.1±3.4
	Imazalil	0.9965	0.00128	0.00388	104.0±2.5
	Imidacloprid	0.9920	0.00154	0.00467	107.0±5.3
	Novaluron	0.9974	0.00082	0.00247	85.0±4.7
	Pyraclostrobin	0.9941	0.00137	0.00416	110.6±5.6
	Sulfoxaflor	0.9971	0.00094	0.00285	93.9±3.4
	Thiabendazole	0.9906	0.00074	0.00225	71.7±2.5

Limit of detection.
Limit of quantification.
Values are mean±RSD (n=3).