Table 4. Occurrence of chlorinated styrenes (CSs)

Country Sample Concentration Reference
Canada Sediment and clam (L. radiata) from 102 Sites; 9 in Detroit River, 24 in St. Clair River, 69 in Lake St. Clair Detroit River; clam OCS (48.7±12.3 ng/g), sediment OCS (1.0±1.2 ng/g), C.F.1) (146.0±102.1 ng/g)St. Clair River; clam OCS (35.9±76.8 ng/g), sediment OCS (14.8±21.4 ng/g), C.F.1) (52.0±46.5 ng/g)Lake St. Clair; clam OCS (43.3±39.6 ng/g), sediment OCS (2.7±4.8 ng/g), C.F.1) (64.0±81.0 ng/g) Pugsley et al. (1985)
Spain Newborn cord sera and maternal sera at 6–8 weeks of pregnancy from Flix (Catalonia, Spain)Top sediments from the Ebro River PeCS; 2.1-540 ng/g in sediments, <0.3 ng/L in mothers, <0.3 ng/L in newborns arterial/cord seraHxCS (11,14,15); 2.7-290 ng/g in sediments, <0.7-6.6 ng/L in mothers, <0.7-3.7 ng/L in newborns arterial sera, <0.7-2.2 ng/L in newborns cord seraHpCS (4,5,6); 27.5-610 ng/g in sediments, <0.7 ng/L in mothers, <0.7 ng/L in newborns arterial/cord seraOCS; 66-15,000 ng/g in sediments, 63 ng/L in mothers, 25/17 ng/L in newborns arterial/cord sera Carrizo et al. (2009)
North sea Water from Elbe estuary, Weser estuary, German BightSediments from German Bight fish liver2) from A, B, C, D, E, F Water: 1.03-1.94 ng/L at Elbe estuary, 0.12 ng/L at weser estuary, 0.03 ng/L at German BightSediment: 0.87-1.32 ng/g at German BightFish liver: 2.0-164.4 ng/g at A, 2.4-27.2 ng/g at B, <1 ng/g at C, N.D. at D, E, F Ernst et al. (1984)
North America Sediment cores from Lake Ontario by the Canada Centre for Inland Waters Eastern: <15 ng/g at 1 site (inlet to the Saint Lawrence River), 15-50 ng/g at 2 sites (from Syracuse, NY, through the Oswego River)Midlike: <15 ng/g at 1 site, >100 ng/g at 1 site (offshore of the Genessee River outlet)Western: <15 ng/g at 2 sites, 15-50 ng/g at 2 sites, 50-100 ng/g at 2 sites (from chlorine plants along the shores of the Niagara River) Kaminsky et al. (1984)
North America Sediment cores from Lake Ontario, mainly in the Niagara basin from the Niagara River HxCSs: 5.9-12 ng/g at 3 sitesHpCSs: 0.1-18 ng/g at 6 sites, Tr3) at 1 siteOCS: 0.3-49 ng/g at 9 sites, Tr3) at 1 site Kaminsky et al. (1984)
North America Water from Lake OntarioBottom/suspended sediments from the Lake Ontario/near the Niagara, Mississauga, and Rochester BasinsPlanktonic/Benthic food chain OCS in Water: 4.7±1.3 pg/LOCS in Sediments: 11±5.1 ng/g in bottom, 4.0±1.2 ng/g in suspendedOCS in the planktonic food chain4), 0.3 ± 0.05 ng/g in plankton, 0.9±0.7 ng/g in mysids (M. relicta), 14 ng/g in alewife, 5.5±1.9 ng/g small smelts, 9.5 ng/g in large smelts, 44±44 ng/g in salmonidsOCS in the benthic food chain5), 6.9±2.9 ng/g in amphipods (P. affinis), 2.5±1.2 in oligochaetes (T. tubifex, L. hoffmeisteri), 16 ng/g in sculpins (C. cognatus), 44±44 ng/g in salmonids Oliver and Niimi (1988)
Norway Fish from the Frierfjord; cod (G. morrhua), coalfish (G. virers), whiting (G. merlangus), pollack (G. pollachius), plaice (P. platessa), eel (A. vulgaris), sprat (C. sprattus) cod: 6.1-92 μg/g of HpCS, 10-361 μg/g of OCScod liver: 44-121 μg/g (1975), 2.3-8.2 μg/g (Sept. 1976), 1.4-16 μg/g (Oct. 1976) of HpCS223-675 μg/g (1975), 12-42 μg/g (Sept. 1976), 16-585 μg/g (Oct. 1976) of OCS cod filet: 26-46 μg/g (May-Sept. 1976), 0.3-24.1 μg/g (Oct.1976) of HpCS 131-169 μg/g (May-Sept. 1976), 3.2-164 μg/g (Oct. 1976) of OCSwhiting: 16-23 μg/g of HCS, 47-87 μg/g of OCSWhiting liver: 2.7-24 μg/g of HpCS, 28-256 μg/g of OCS (Oct. 1976)Whiting filet: 0.9-15 μg/g of HpCS, 12-165 μg/g of OCS (Oct. 1976)pollack liver: 1.4-3.7 of HCS, 4-11 of OCSpollack filet: 13-14 of HCS, 7-50 of OCSplaice: 11-18 (Sept. 1975), 1.7-19 (May. 1976) of HpCS 15-18 (Sept. 1975), 21-91 (May. 11976) of OCSeel: 1.9-3.2 (Sept. 1975), 1.4-4.7 (May-Sept. 1976) of HpCS 5.0-6.5 (Sept. 1975), 8-25 (May-Sept. 1976) of OCSSprat: 3.9-12 of HpCS, 10-40 of OCS Ofstad et al. (1978)
Norway Fish from the Eidangerfjord (near the fijord); cod (G. morrhua), pollack (G. pollachius), sprat (C. sprattus) cod liver: 2.0-3.8 μg/g of HpCS, 6.2-21 μg/g of OCS, cod filet: 0.7-2.5 μg/g of HpCS, 2.9-3.3 μg/g of OCSpollack liver: 1.4-4.1 of HpCS, 5.1-14 of OCS, pollack filet: 0.8-1.1 of HpCS, 3.1-5.2 of OCSsprat: 0.6-2.3 of HCS, 3.6-6.4 of OCS Ofstad et al. (1978)
North America Lake trout (S. namaycush) whitefish (C. culpeaformis) obtained from Siskiwit Lake, Isle Royale, Lake Superior OCS in Lake trout: 13 ng/g (SM6) & MED7)), 17 ng/g (LG8)), 32 ng/g (XLG9)), 19 ng/g lipid (mean)OCS in Whitefish: 12 ng/g (SM), 24 ng/g (MED), 13 ng/g (LG), 16 ng/g lipid (mean) Swackhamer and Hites (1988)
North America Native mussels (F. Unionidae) from 20 stations in the Ottawa and St. Lawrence Rivers upper St. Lawrence River: 0.06 ng/g (L10)) in BP, 0.05 ng/g (E11)) in 29Lac Saint-Francois: 0.07 ng/g (E) in 42Lac Saint-Louis: 0.04 ng/g (E), 0.03-0.08 ng/g (L) in 55, 0.17-0.21 ng/g (L) in 59Lac Saint-Pierre: 0.05 ng/g (E) in 103, 0.05 ng/g (E) in 107, 0.16 ng/g (L) in 112 Metcalfe and Charlton (1990)
North America Fish from Great Lakes, also include Lake St. Clair, the Ashtabula River and Fields Brook of Ohio Lake Superior Apostle Islands, WI; Copper Harbor, MI, Lake Michigan Grand Traverse Bay, MI, Lake Huron Mackinac, MI: ND12)Lake Huron Saginaw Bay, MI: 2.0-110.7 ng/gLake Erie Woodtic, MI: 33.8 ng/gLake Ontario Cape Vincent, NY; Oswego, NY; Stony Island, NY: 28.1-86 ng/gLake St.Clair Anchor Bay, MI: 227 ng/gAshtabuka River, OH: NQ13)-405 ng/gFields Brook, OH: 184-256 ng/g Kuehl et al. (1981)
Norway Sprat (C. sprattus) from south-eastern Norway; around Frierfjorden contaminated by chlorinated compounds from one main source. Sprat (C. sprattus) from Norwegian west coast as background Frierfjorden: 8.8 μg/g (June 74), 11.2 μg/g (Sept 75) of OCS, 2.9 μg/g (June 74), 4.0 μg/g (Sept 75) of HpCSEidangerfjorden: 3.8 μg/g of OCS, 1.1 μg/g of HpCS (Sept 75)Ormefjorden: 2.0 μg/g of OCS, 0.6 μg/g of HpCS (Sept 75)Sandefjord: <0.1 μg/g of OCS, <0.02 μg/g of HpCS (Sept 75)Torvik, Romsdal: - of OCS, - of HpCS (Sept 75) Lunde and Ofstad (1976)
C.F., chemical concentration factor, i.e., chemical concentration in clam dry weight/sediment dry weight.
Fish liver: A, North sea, German Bight (south of Helgoland); B, North sea, 55° 30’N:04° 50’E/06° 03’E; C, North Atlantic, Fiskenaes Bank (west of Greenland), D, North Atlantic, Tenerife, local fishery; E, Eastern Mediterranean, Methoni, Greece, local fishery; F, Red sea, Hurghada, local fishery.
Tr, trace abundance.
Planktonic food chain: Water - plankton (from each major basins) - mysid (M. relicta, from Niagar and Rochester Basin of the lake) - alewive and rainbow smelt (from Vineland, Port Credit) - salmonid (O. velinus, S. gairdneri, S. namaycush, S. trutta from Credit River and Vineland).
Benthic food chain: Water - sediment - amphipod (P. affinis from Niagara River) / oligochaete (T. tubifex, L. hoffmeisteri from Niagara River) - sculpin (C. cognatus from near Grimsby) - salmonid (O. velinus, S. gairdneri, S. namaycush, S. trutta from Credit River and Vineland).
SM, small size.
MED, medium size.
LG, large size.
XLG, x-large size.
L, Lampsilis radiata radiata.
E, Elliptio complanata.
ND, not detected; detection limit 1 ng/g wet weight whole fish.
NQ, detected but not quantifiable.