Table 1. Compounds identified in total essential oil of fresh ginseng root
Peak no. | RT1) (min) | Compound2) | m/z | RI3) | Peak area (%)4) |
1 | 6.12 | α-Pinene | 136 | 1,001 | 1.63 |
2 | 7.45 | Camphene | 136 | 1,072 | 0.37 |
3 | 8.93 | β-Pinene | 136 | 1,121 | 3.97 |
4 | 9.46 | Sabinene | 136 | 1,136 | 0.05 |
5 | 11.31 | Myrcene | 136 | 1,138 | 0.70 |
6 | 12.10 | α-Phellandrene | 136 | 1,193 | 0.07 |
7 | 12.42 | Limonene | 136 | 1,212 | 0.13 |
8 | 12.97 | β-Phellandrene | 136 | 1,222 | 0.14 |
9 | 17.50 | p-Cymene | 134 | 1,295 | 0.05 |
10 | 21.47 | n-Hexanol | 102 | 1,364 | 0.06 |
11 | 25.06 | Clovene | 204 | 1,421 | 0.66 |
12 | 26.83 | δ-Elemene | 204 | 1,451 | 1.63 |
13 | 28.11 | α-Cubebene | 204 | 1,472 | 0.38 |
14 | 29.18 | α-Ylangene | 204 | 1,487 | 0.06 |
15 | 29.50 | Amorphene | 204 | 1,493 | 0.44 |
16 | 29.93 | α-Copaene | 204 | 1,498 | 0.51 |
17 | 30.10 | Bicycloelemene | 204 | 1,503 | 0.47 |
18 | 31.48 | α-Bourbonene | 204 | 1,525 | 0.45 |
19 | 31.38 | β-Ylangene | 204 | 1,530 | 0.13 |
20 | 32.17 | β-Panasinsene | 204 | 1,536 | 7.53 |
21 | 32.69 | Longipinene | 204 | 1,545 | 0.53 |
22 | 33.22 | α-Gurjunene | 204 | 1,554 | 1.25 |
23 | 34.86 | cis-α-Bergamotene | 204 | 1,580 | 0.25 |
24 | 35.92 | β-Elemene | 204 | 1,596 | 0.57 |
25 | 36.42 | β-Caryophyllene | 204 | 1,602 | 8.24 |
26 | 36.88 | Guaiene | 204 | 1,607 | 0.87 |
27 | 37.05 | Aromandendrene | 204 | 1,609 | 0.44 |
28 | 38.66 | α-Panasinsene | 204 | 1,636 | 5.14 |
29 | 39.44 | α-Neoclovene | 204 | 1,646 | 7.78 |
30 | 39.57 | allo-Aromandendrene | 204 | 1,650 | 1.24 |
31 | 40.03 | γ-Gurjunene | 204 | 1,656 | 0.14 |
32 | 41.19 | α-Humulene | 204 | 1,671 | 13.91 |
33 | 41.55 | Selina-4,11-diene | 204 | 1,676 | 4.62 |
34 | 42.44 | β-Neoclovene | 204 | 1,701 | 1.62 |
35 | 42.85 | Germacrene B | 204 | 1,706 | 0.35 |
36 | 43.52 | γ-Cadinene | 204 | 1,721 | 0.20 |
37 | 43.99 | β-Selinene | 204 | 1,731 | 0.49 |
38 | 44.30 | α-Selinene | 204 | 1,736 | 0.63 |
39 | 44.92 | Bicyclogermacrene | 204 | 1,748 | 13.59 |
40 | 46.34 | γ-Bisabolene | 204 | 1,771 | 0.35 |
41 | 46.53 | β-Sesquiphellandrene | 204 | 1,775 | 0.65 |
42 | 49.41 | ar-Curcumene | 202 | 1,824 | 0.06 |
43 | 52.86 | β-Phenylethyl alcohol | 122 | 1,866 | 0.15 |
44 | 53.79 | Calacorene | 200 | 1,893 | 0.11 |
45 | 57.31 | Nerolidol | 222 | 1,972 | 0.82 |
46 | 61.46 | Panasinsenol A | 222 | 2,052 | 0.68 |
47 | 61.72 | Panasinsenol B | 222 | 2,057 | 2.17 |
48 | 63.26 | Globulol | 222 | 2,087 | 0.53 |
49 | 63.73 | Ledol | 222 | 2,096 | 0.51 |
50 | 64.29 | α-Eudesmol | 222 | 2,119 | 0.07 |
52 | 64.87 | β-Eudesmol | 222 | 2,106 | 0.09 |
52 | 66.39 | Spathulenol | 220 | 2,192 | 1.65 |
53 | 66.59 | Neointermedeol | 222 | 2,153 | 2.20 |
54 | 66.89 | Ginsenol | 222 | 2,155 | 1.69 |
55 | 68.16 | τ-Cadinol | 222 | 2,187 | 0.13 |
56 | 68.84 | α-Cadinol | 222 | 2,204 | 0.10 |
57 | 69.53 | Torreyol | 222 | 2,213 | 0.08 |
58 | 70.77 | Methyl palmitate | 270 | 2,241 | 0.67 |
59 | 73.26 | Farnesol | 222 | 2,294 | 0.29 |
60 | 76.20 | Methyl linoleate | 294 | 2,360 | 0.38 |
61 | 86.60 | Myristic acid | 228 | >2,600 | 0.83 |
62 | 97.87 | Palmitic acid | 256 | >2,600 | 0.78 |
63 | 102.34 | Panaxynol | 244 | >2,600 | 0.95 |
Total | 97.23 |
RT, retention time.
Searching of NIST mass spectral library and NIST Chemistry Webbook.
Retention indices on polar Supelcowax 10 capillary column.
Peak area (%) in total essential oil of fresh ginseng root.