Table 1. Compounds identified in total essential oil of fresh ginseng root

Peak no. RT1) (min) Compound2) m/z RI3) Peak area (%)4)
1 6.12 α-Pinene 136 1,001 1.63
2 7.45 Camphene 136 1,072 0.37
3 8.93 β-Pinene 136 1,121 3.97
4 9.46 Sabinene 136 1,136 0.05
5 11.31 Myrcene 136 1,138 0.70
6 12.10 α-Phellandrene 136 1,193 0.07
7 12.42 Limonene 136 1,212 0.13
8 12.97 β-Phellandrene 136 1,222 0.14
9 17.50 p-Cymene 134 1,295 0.05
10 21.47 n-Hexanol 102 1,364 0.06
11 25.06 Clovene 204 1,421 0.66
12 26.83 δ-Elemene 204 1,451 1.63
13 28.11 α-Cubebene 204 1,472 0.38
14 29.18 α-Ylangene 204 1,487 0.06
15 29.50 Amorphene 204 1,493 0.44
16 29.93 α-Copaene 204 1,498 0.51
17 30.10 Bicycloelemene 204 1,503 0.47
18 31.48 α-Bourbonene 204 1,525 0.45
19 31.38 β-Ylangene 204 1,530 0.13
20 32.17 β-Panasinsene 204 1,536 7.53
21 32.69 Longipinene 204 1,545 0.53
22 33.22 α-Gurjunene 204 1,554 1.25
23 34.86 cis-α-Bergamotene 204 1,580 0.25
24 35.92 β-Elemene 204 1,596 0.57
25 36.42 β-Caryophyllene 204 1,602 8.24
26 36.88 Guaiene 204 1,607 0.87
27 37.05 Aromandendrene 204 1,609 0.44
28 38.66 α-Panasinsene 204 1,636 5.14
29 39.44 α-Neoclovene 204 1,646 7.78
30 39.57 allo-Aromandendrene 204 1,650 1.24
31 40.03 γ-Gurjunene 204 1,656 0.14
32 41.19 α-Humulene 204 1,671 13.91
33 41.55 Selina-4,11-diene 204 1,676 4.62
34 42.44 β-Neoclovene 204 1,701 1.62
35 42.85 Germacrene B 204 1,706 0.35
36 43.52 γ-Cadinene 204 1,721 0.20
37 43.99 β-Selinene 204 1,731 0.49
38 44.30 α-Selinene 204 1,736 0.63
39 44.92 Bicyclogermacrene 204 1,748 13.59
40 46.34 γ-Bisabolene 204 1,771 0.35
41 46.53 β-Sesquiphellandrene 204 1,775 0.65
42 49.41 ar-Curcumene 202 1,824 0.06
43 52.86 β-Phenylethyl alcohol 122 1,866 0.15
44 53.79 Calacorene 200 1,893 0.11
45 57.31 Nerolidol 222 1,972 0.82
46 61.46 Panasinsenol A 222 2,052 0.68
47 61.72 Panasinsenol B 222 2,057 2.17
48 63.26 Globulol 222 2,087 0.53
49 63.73 Ledol 222 2,096 0.51
50 64.29 α-Eudesmol 222 2,119 0.07
52 64.87 β-Eudesmol 222 2,106 0.09
52 66.39 Spathulenol 220 2,192 1.65
53 66.59 Neointermedeol 222 2,153 2.20
54 66.89 Ginsenol 222 2,155 1.69
55 68.16 τ-Cadinol 222 2,187 0.13
56 68.84 α-Cadinol 222 2,204 0.10
57 69.53 Torreyol 222 2,213 0.08
58 70.77 Methyl palmitate 270 2,241 0.67
59 73.26 Farnesol 222 2,294 0.29
60 76.20 Methyl linoleate 294 2,360 0.38
61 86.60 Myristic acid 228 >2,600 0.83
62 97.87 Palmitic acid 256 >2,600 0.78
63 102.34 Panaxynol 244 >2,600 0.95
Total 97.23
RT, retention time.
Searching of NIST mass spectral library and NIST Chemistry Webbook.
Retention indices on polar Supelcowax 10 capillary column.
Peak area (%) in total essential oil of fresh ginseng root.