Table 4
LOD and LOQ of the hazardous metals according to different migrant solution at 100°C for 30 min (μg/kg)

Parameter Distilled water Citric acid solution (0.5%) NaCl solution (1%)
LOD1) LOQ2) LOD LOQ LOD LOQ
Pb 2.48 8.81 1.02 3.36 2.84 9.37
As 2.00 6.59 1.66 5.47 2.46 8.11
Cd 0.45 1.48 0.47 1.56 0.53 1.75
Ni 0.57 1.89 0.28 0.91 1.42 4.68
Al 3.95 13.02 1.60 5.30 1.80 5.95
Limit of detection=3×σ/m (σ, standard deviation of area; m, slope of calibration curve).
Limit of quantification=3.3×LOD.